Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)-Reference-Cited by-同舟云学术

Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)

Published:2012-08 Issue:8 Volume:90 Page:693-700
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Lundrigan Travis¹,Jackson Carla L.M.¹,Uddin Md. Imam¹,Tucker Lloyd A.¹,Ali Adeeb Al-Sheikh¹²,Linden Anthony³,Cameron T. Stanley¹,Thompson Alison¹

Affiliation:

1. Department of Chemistry, Dalhousie University, PO BOX 15000, Halifax, NS B3H 4R2, Canada.

2. Chemistry Department, Taibah University, Almadinah Almunawarah, P.O. Box 30002, Saudi Arabia.

3. Institute of Organic Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland.

Abstract

The synthesis and characterization of the first heteroleptic pyrrolide/2,2′-bipyridyl complexes of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react with Ru(bipy)2Cl2·2H2O to form complexes in which the pyrrolide ligands chelate to Ru(II). The library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl derivatives.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v2012-045

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