The preparation and kinetics of complex formation of hexadimethylsulfoxidovanadium(III) perchlorate-Reference-Cited by-同舟云学术

The preparation and kinetics of complex formation of hexadimethylsulfoxidovanadium(III) perchlorate

Published:1970-10-01 Issue:19 Volume:48 Page:2969-2971
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Langford Cooper H.,Chung Fine Man

Abstract

We report the synthesis of the ion V(DMSO)63+ and kinetics of its reactions with SCN−, sulfosalicylic acid, and 2,2-bipyridine. The complex formation rates show some dependence on the ligand. The value of ΔS≠ found for the reaction with bipyridine is quite negative. A definite mechanistic assignment cannot yet be made.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v70-502

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