Ligand redistribution hinders preparation of a nickel(II)-hydroxo

Abstract

The synthesis is demonstrated for a heteroleptic Ni(II) complex, with a tridentate ligand bearing N-heterocyclic carbene (NHC), aryloxide, and picolyl donor groups. The compound was reacted with a variety of hydroxide sources, several of which resulted in complex mixtures. Reaction with [NH4]OH affords a bis-ligated nickel compound, in which the ligands are each bound in a bidentate fashion through the NHC and aryloxide donor groups. A desired nickel(II)-hydroxo product was not observed. DFT studies suggest that ligand redistribution is thermodynamically preferred over stabilization of a Ni-hydroxo in either a monomeric or dimeric form.