Abstract
The A2Π–X2Σ, and B2Σ–X2Σ, transitions of ScS were observed in the near infrared. The vibrational quantum numbers of the A2Π state could not be determined absolutely because of the lack of sensitivity of the film at the longer wavelengths. The vibrational constants for the X (ωe = 565.2 cm−1) and B (ωe = 488.2 cm−1) states were deduced from the band heads.
Publisher
Canadian Science Publishing
Subject
General Physics and Astronomy
Cited by
8 articles.
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1. Electronic states, spectroscopic parameters, transition probabilities, and radiative lifetimes of the scandium monosulfide cation, ScS+: A theoretical contribution;Computational and Theoretical Chemistry;2019-06
2. Transition moments, radiative transition probabilities, and radiative lifetimes for the band systems A 2 Π–X 2 Σ + , B 2 Σ + –X 2 Σ + , and A 2 Π–A´ 2 Δ of scandium monosulfide, ScS;Journal of Quantitative Spectroscopy and Radiative Transfer;2018-05
3. How To Arrive at Accurate Benchmark Values for Transition Metal Compounds: Computation or Experiment?;Journal of Chemical Theory and Computation;2017-10-13
4. A study of the A2Π–X2Σ+ and B2Σ+–X2Σ+ band systems of scandium monosulfide, ScS, using Fourier transform emission spectroscopy and laser excitation spectroscopy;Journal of Molecular Spectroscopy;2006-05
5. Dipole moments and hyperfine interactions in scandium monosulfide, ScS;The Journal of Chemical Physics;1997-12-22