NEW CONSIDERATIONS IN ORGANOGERMANIUM-SULPHUR CHEMISTRY

Author:

Henry Malcolm C.,Davidson Wenzel E.

Abstract

The successful synthesis of sodium triphenylgermanethiol (1), (C6H5)3GeSNa, and disodium diphenylgermanedithiol, (C6H5)2Ge(SNa)2, have made it possible to carry out reactions with RX type compounds yielding a variety of organogermanium-sulphur compounds. In addition, triphenylgermanethiol, (C6H5)3GeSH, has been synthesized for the first time. Reactions of these compounds are related to analogous group IV element compounds. Physical and chemical properties of these new compounds are also discussed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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1. Benzylgermanium Compounds as Modifiers of Silica Gel Surface During a Chromatographic Process;Critical Reviews in Analytical Chemistry;2010-07-30

2. Problems Associated with the Chromatographic Determination of Chlorobenzylgermanium Derivatives Using an Octadecyl Stationary Phase;Critical Reviews in Analytical Chemistry;2010-01-29

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