Author:
Paryzek Zdzisław,Wydra Roman
Abstract
The boron trifluoride etherate catalyzed rearrangement of 3β-acetoxy-9α, 11α-epoxy-5α-lanostan-7-one (1) in acetic anhydride resulted in formation of 19(10 → 9β)abeo compounds 2 and 4 along with 18(13 → 12β)abeo compound 5, as the major product. These structures are supported by spectral data and chemical transformations. The possible mechanism of the rearrangement is discussed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
9 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献