EXCEPTIONS TO HUDSON'S RULES OF ISOROTATION: THE NUCLEAR MAGNETIC RESONANCE SPECTRA OF ANOMERIC PYRIMIDINE 2-DEOXY-D-RIBONUCLEOSIDES-Reference-Cited by-同舟云学术

EXCEPTIONS TO HUDSON'S RULES OF ISOROTATION: THE NUCLEAR MAGNETIC RESONANCE SPECTRA OF ANOMERIC PYRIMIDINE 2-DEOXY-D-RIBONUCLEOSIDES

Published:1961-01-01 Issue:1 Volume:39 Page:110-115
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Lemieux R. U.,Hoffer M.

Abstract

Nuclear magnetic resonance spectroscopy and optical rotatory dispersion measurements were used to correlate the configurations of anomeric pairs for the 1-(2-deoxy-D-ribofuranosyl) derivatives of 5-methyl- and 5-fluoro-uracil. The optical rotations of the anomers were found opposite to those expected on the basis of Hudson's rules of isorotation.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v61-013

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