Author:
Jarvie J. M. S.,Cvetanović R. J.
Abstract
Reactions of oxygen activated by electrical discharge with butene-1 have been studied in a "spherical diffusion" reaction zone. When small concentrations of oxygen are passed through the discharge tube in helium as the carrier gas, and the concentration of butene-1 in the reaction zone is sufficiently high, the observed products are entirely explainable by an interaction of the ground-state oxygen atoms with butene-1. With large deviations from these conditions considerable complexities arise, and under some conditions α-butylene ozonide and its decomposition products become important and the products are then explainable without any significant participation of oxygen atoms in the process.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
25 articles.
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1. Ethylene Oxides;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02
2. Addition of Atoms to Olefins in the Gas Phase;Advances in Photochemistry;2007-01-05
3. O(3P) reactions with small alkenes adsorbed on Rh, Au, and ice;Surface Science;2006-03
4. Reactions of O(3 P) with aromatic compounds in the liquid phase;Plasma Chemistry and Plasma Processing;1996-12
5. Application of cold plasma in organic reaction.;Journal of Synthetic Organic Chemistry, Japan;1986