Author:
Edward J. T.,Chang H. S.,Samad S. A.
Abstract
In inert solvents in the presence of aluminum chloride, aroyl peroxides decompose to esters and carbon dioxide. In highly nucleophilic solvents such as anisole or mesitylene, p,p′-dinitrobenzoyl peroxide effects a Friedel–Crafts type of substitution of the solvent molecule. Both decomposition and substitution reactions probably depend on a heterolytic fission of the peroxide linkage catalyzed by aluminum chloride.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
37 articles.
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