Author:
MacLaurin Donald J.,Green John W.
Abstract
Rates of isomerization, epimerization, and degradation reactions were measured for D-glucose (1), D-fructose (2), and D-mannose (3) at 0.002 M in 1 M NaOH under N2 in the dark at 22 °C. Reaction system resolution was by column chromatography on anion resins in the borate form. Assay for 1, 2, and 3 was by continuous automated colorimetry of column effluent using orcinol/sulfuric acid as a reagent. D-Allose and D-altrose were not detected. Reaction rate constants (h−1) found: k12 0.038, k13 0.0005, k15 0.002, k21 0.036, k23 0.006, k24 0.072, k31 0.0005, k32 0.011, k36 0.002, where 4, 5, and 6 are products formed from 1, 2, or 3, respectively.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
29 articles.
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