THE NUMBER-AVERAGE AND WEIGHT-AVERAGE MOLECULAR WEIGHT OF SOME NONIONIC SURFACE-ACTIVE AGENTS

Author:

Sirianni A. F.,Cowie J. M. G.,Puddington I. E.

Abstract

Further evidence for the existence of large differences between the weight- and number-average molecular weight for nonionic surface-active substances in nonaqueous solvents has been found when the property is assessed by light-scattering and vapor-pressure-lowering measurements. Equilibrium ultracentrifuge measurements support the results obtained by vapor-pressure-lowering determinations. Sorbitan and glycerol monostearates have been examined in benzene solution.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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1. Aggregation behavior of alkylethylenediamine palladium(II) complexes in water and in water/organic solvent mixtures;Colloids and Surfaces A: Physicochemical and Engineering Aspects;2007-07

2. The Aggregation of Dichlorobis(N-hexylethylenediamine)zinc(II) in Water and Water/Chloroform Mixed Solvents;Bulletin of the Chemical Society of Japan;2002-03

3. The structure of micelles and microemulsions;Reports on Progress in Physics;1990-03-01

4. Micellization;Surfactant Systems;1983

5. Solubilization of silver stearate by nonionic surfactants in organic solvents;Journal of Colloid and Interface Science;1980-09

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