STEREOCHEMICAL STUDIES: II. CONFIGURATIONS OF SOME 4-OXACHOLESTANES-Reference-Cited by-同舟云学术

STEREOCHEMICAL STUDIES: II. CONFIGURATIONS OF SOME 4-OXACHOLESTANES

Published:1960-08-01 Issue:8 Volume:38 Page:1325-1330
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Edward J. T.,Morand Peter F.

Abstract

The oxidation of A-nor-5β-cholestan-3-one with peracids gave 4-oxa-5β-cholestan-3-one. This was identical with one of the two lactones produced by the reduction of Windaus' keto acid; the other lactone must be 4-oxa-5α-cholestan-3-one. The two lactones were reduced by lithium aluminum hydride to diols, which were cyclized to 4-oxa-5α- and -5β-cholestane.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v60-186

Reference16 articles.

1. Steroids Labeled with Isotopic Carbon: Cholestenone and Testosterone1

2. Ueber Cholesterin

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