Improvement in aerobic sludge digestion through pH control: initial assessment of pilot-scale studies

Abstract

Waste-activated sludges from an extended-aeration, pilot-scale wastewater treatment facility and a high-rate, full-scale system were aerobically digested in 150 L pilot-scale digesters, operated in a semicontinuous (daily fill-and-draw) mode, at a standard 15-day solids retention time (SRT). To offset the mixed-liquor pH (MLpH) decrease normally encountered in these digesters (as a result of nitrification), hydrated lime and sodium bicarbonate were used in separate experiments to control MLpH in the series pH 6, 7, 8, and 9. Digester performance in the first stage of this work was assessed solely on the basis of reduction in total volatile suspended solids.The extended-aeration type sludge exhibited the greatest improvement in process performance under all pH-controlled conditions. Improvements in digestion efficiency of up to 80% over the uncontrolled reactors were noted. The use of lime resulted in greater digestion enhancement than did sodium bicarbonate with this sludge, without a significant increase in sludge solids production (owing to the low chemical doses required). Digestion efficiency of the high-rate type sludge was little improved (on a relative basis) with either chemical; however, absolute efficiencies in the individual digesters were, in some cases, nearly double those of the comparative extended-aeration sludge digesters. This difference appears to be a function of the process from which the digesting sludge originated, and seems to be influenced by the amount of easily oxidizable, endogenous substrate contained in the biomass. It was concluded that the extended-aeration type sludge was most amenable to enhanced digestion through pH control; as well, cost and process considerations made lime the chemical of choice. Key words: activated sludge, aerobic digestion, hydrated lime, mixed-liquor pH control, nitrification, process enhancement, pilot-scale, sodium bicarbonate.