Abstract
The reaction of alkali metals with tertiary alkyl nitriles eventually gives, after protonation, an imine. α-tert-Alkylketones are produced by the hydrolysis of these imines. This reaction, involving radical anion intermediates, is a simple method for the synthesis of highly hindered symmetric ketones.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
11 articles.
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