Author:
Palmer T. F.,Lossing F. P.
Abstract
In the reaction of isobutane with Hg3P1 atoms, cleavage of the tertiary C—H bond is about seven times as frequent as cleavage of a primary C—H bond. This ratio is greatly changed by deuterium substitution in the tertiary position. Cleavage of the tertiary C—D bond in (CH3)3CD occurs only about 0.6 times as frequently as cleavage of a primary C—H bond. In (CD3)3CH, no cleavage of a primary C—D bond could be detected, and only the tertiary H-atom is removed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
3 articles.
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