Author:
Grignon-Dubois Micheline,Fialeix Michelle,Leger Jean-Michel
Abstract
Silylation of isoquinoline with Me3SiCl/Li/THF or Me3SiCl/Mg/THF reagents has been studied. The choice of the metal and the experimental conditions govern the course of the silylation reaction and lead to new trimethylsilyl heterocyclic compounds.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
11 articles.
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1. Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent;Tetrahedron;2015-02
2. ChemInform Abstract: Silylation of Isoquinoline: The Influence of Experimental Conditions on the Formation of New Trimethylsilyl Heterocyclic Compounds.;ChemInform;2010-08-20
3. (1R,1′R)-1,1′,2,2′,3,3′,4,4′-Octahydro-1,1′-biisoquinoline;Encyclopedia of Reagents for Organic Synthesis;2007-03-15
4. (1R,1′R)-1,1′,2,2′,3,3′,4,4′-Octahydro-1,1′-biisoquinoline;Encyclopedia of Reagents for Organic Synthesis;2007-03-15
5. Synthetic approaches to carnegine, a simple tetrahydroisoquinoline alkaloid;Tetrahedron;2004-11