Author:
Heckley P. R.,Holah D. G.,Hughes A. N.,Leh F.
Abstract
Sodium N,N-diethyldithiocarbamate reacts smoothly with methylene chloride (even in the presence of various transition metal ions) to give the dithiocarbamate ester Et2NC(S)SCH2S(S)CNEt2 in very high yield. With chloroform and acetonitrile, proton abstraction occurs followed by partial decomposition of the N,N-diethyldithiocarbamic acid so formed to give diethylammonium N,N-diethyldithiocarbamate.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
10 articles.
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