Sulfoxydes et sulfones hétérobicycliques dérivés de l'α-thioglycérol. 2,8-Dioxa-6-oxo-6-thiabicyclo[3.2.1]octanes et 2,8-dioxa-6,6′-dioxo-6-thiabicyclo[3.2.1]octanes

Abstract

The oxidation reactions of heterobicyclic sulfides derived from α-thioglycerol (alkyl-2,8-dioxa-6-thiabicyclo[3.2.1]octanes), leading to sulfoxides and the corresponding sulfones, have been studied. The stereochemistry of the oxidation as a function of the reagent used (H2O2, meta-chloroperbenzoic acid, and tert-butyl hypochlorite) has been examined. Structural assignments of the sulfoxides arise from the spectroscopic and chemical properties of these compounds. [Journal translation]