Synthesis of (±)-trixagol by an electrophilic cyclization of an allylsilane-Reference-Cited by-同舟云学术

Synthesis of (±)-trixagol by an electrophilic cyclization of an allylsilane

Published:1983-11-01 Issue:11 Volume:61 Page:2530-2539
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Armstrong Rosemary J.,Weiler Larry

Abstract

1,5-Dienes containing an allylsilane are cyclized by Lewis acids to methylenecyclohexanes. The trimethylsilyl group exerts a strong activating and directing influence on the regioselectivity of this cyclization. The monocyclic compound 10 was converted into the diterpene, (±)-trixagol (3).[Formula: see text]

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v83-436

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