Author:
Martak Fahimah,Fansuri Hamzah,Putri Sekarayu Dianing
Abstract
Binuclear complex, [N(n-C4H9)4][MnIIFeIII(ox)3] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C4H9)4][MnIIFeIII(ox)3] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characterization of the complex was made by microanalysis, FT-IR spectroscopy, x-ray diffraction and Magnetic Susceptibility Balance. Magnetic moment of binuclear complex [N(n-C4H9)4][MnIIFeIII(ox)3] is 7.81 BM. The compound has higher magnetic moment than the previously reported compound with different organic cation, [N(n-C5H11)4][MnIIFeIII(ox)3]. This behavior might be associated with the decreasing range among layers on polymeric network.
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1 articles.
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1. Synthesis, characterization and application of complex compounds: Review of studies among Indonesian scholars;THE 5TH INTERNATIONAL CONFERENCE ON MATHEMATICS AND SCIENCE EDUCATION (ICoMSE) 2021: Science and Mathematics Education Research: Current Challenges and Opportunities;2023