A Molecular Level Study of Water-Oil Interface in the CO2 EOR Under Low Pressure Condition

Abstract

Abstract In this study, molecular dynamics simulations have been performed to study the interfacial properties between water and oil with different mole fractions of CO2 under 8 MPa and 345 K. Simulation results show that with the increase of CO2 mole fraction, more CO2 got adsorbed in the water-oil interface region. Such CO2 increase weakened water and oil interactions at the interface, resulting in a decrease of the interfacial tension (IFT). Moreover, the water-oil IFT decreased significantly from 0 to 0.40 CO2 mole fractions. But the change was small for higher CO2 mole fractions of 0.40 to 0.80. From those calculations, we conclude that in the CO2-EOR, the volume of injected CO2 needs to be at least more than 0.4 mole fraction (to the oil) to achieve a decent reduction of the water-oil IFT. This study can provide a molecular level reference for implementing the CO2-EOR in the oil field under a low-pressure condition.