Detection of Iron Disulfide Materials in Geological Porous Media Using Spectral Induced Polarization Method

Abstract

Summary Iron sulfide (FeS) scale is a known problem that can significantly impact oil and gas (O&G) production. However, current monitoring methods cannot detect the problem at early stages, not until it is too late for any meaningful remedial action. Spectral induced polarization (SIP) is an established geophysical method increasingly used in near-surface environmental applications. The unique characteristics of the SIP method, mainly the sensitivity to both bulk and interfacial properties of the medium, allow for the potential use as a characterization and monitoring tool. SIP is particularly sensitive to metallic targets, such as FeS, with direct implications for the detection, characterization, and quantification of FeS scale. In a column setup, various concentrations of pyrite (FeS2), a common form of FeS scale, within calcite were tested to examine the SIP sensitivity and establish qualitative and quantitative relationships between SIP signals and FeS2 properties. The concentration of FeS2 in the samples directly impacts the SIP signals; the higher the concentration, the higher the magnitude of SIP parameters. Specifically, the SIP method detected the FeS2 presence as low as 0.25% in the bulk volume of the tested sample. This study supports the potential use of SIP as a detection method of FeS2 presence. Furthermore, it paves the way for upcoming studies utilizing SIP as a reliable and robust FeS scale characterization and monitoring method.