Alkaline Surfactant-Polymer Formulation Evaluation in Live Oil Conditions: The Impact of Temperature, Pressure and Gas on Oil Recovery Performance

Abstract

Abstract An Alkaline-Surfactant-Polymer / Surfactant-Polymer (ASP/SP) design study generally includes intensive work. Hundreds formulations have to be tested to screen phase behavior and typically a dozen of corefloods are performed to select the best formulation and further optimize the injection strategy/slugs design to match economic criteria. To be extrapolated to the field, it is critical to perform these tests in conditions as close as possible to real reservoir conditions: reservoir temperature, injection brine, reservoir pressure and reservoir oil. Specifically, dissolved gas and high-pressure tend to significantly impact crude oil properties, and subsequently formulation behavior and performance, even when limited amount of gas is present. Ideally, this parameter should be considered from the beginning of the formulation design. However, considering the high number of tests to perform, as well as the relatively high cost and technical challenges associated with live oil experiments, it is unrealistic to routinely perform all the required experiments in high-pressure environment. We will present here the methodology developed to design surfactant based process by mimicking the impact of reservoir gas and pressure on the reservoir stock-tank oil. First a thermodynamic model based on an equation of state is fitted to reservoir PVT data (Gas/Oil Ratio or GOR, stocktank oil and associated gas composition analysis, bubble pressure and volumetric factor Bo) to predict consistent thermodynamic behavior and properties of the live oil. This step allows us to validate the reservoir conditions. A recombination of stock-tank oil with gas should be then performed to obtain the fluid in the reservoir conditions. Then we will illustrate through case studies how to combine a high-throughput robotic platform and a high-pressure/high-temperature cell to determine a representative crude oil matching live oil main properties, namely viscosity and Equivalent Alkane Carbon Number (EACN). This representative crude oil is obtained from the reservoir stock-tank oil which has been adjusted, using solvents or alkanes, to present the same characteristics as the reservoir live oil. This oil will therefore be used for an exhaustive formulation design and process optimization. Finally, we will compare oil recovery performances with the representative crude oil and with the reservoir live oil.