Scale Prediction and Inhibition for Oil and Gas Production at High Temperature/High Pressure

Abstract

Summary With the advance of new exploration and production technologies, oil and gas production has gone to deeper and tighter formations than ever before. These developments have also brought challenges in scale prediction and inhibition, such as the prevention of scale formation at high temperatures (150–200°C), pressures (1,000–1,500 bar), and total dissolved solids (TDS) (>300,000 mg/L) commonly experienced at these depths. This paper will discuss (1) the challenges of scale prediction at high temperatures, pressures, and TDS; (2) an efficient method to study the nucleation kinetics of scale formation and inhibition at these conditions; and (3) the kinetics of barite-crystal nucleation and precipitation in the presence of various scale inhibitors and the effectiveness of those inhibitors. In this study, nine scale inhibitors have been evaluated at 70–200°C to determine if they can successfully prevent barite precipitation. The results show that only a few inhibitors can effectively inhibit barite formation at 200°C. Although it is commonly believed that phosphonate scale inhibitors may not work for high-temperature inhibition applications, the results from this study suggest that barite-scale inhibition by phosphonate inhibitors was not impaired at 200°C under strictly anoxic condition in NaCl brine. However, phosphonate inhibitors can precipitate with Ca2+ at high temperatures and, hence, can reduce efficiency. In addition, the relationships of scale inhibition to types of inhibitors and temperature are explored in this study. This paper addresses the limits of the current predition of mineral solubility at high-temperature/high-pressure (HT/HP) conditions and sheds light on inhibitior selection for HT/HP application. The findings from this paper can be used as guidelines for applications in an HT/HP oilfield environment.