Optimum Injection Rate of A New Chelate That Can Be Used To Stimulate Carbonate Reservoirs

Abstract

Summary Different chelating agents were used as alternatives for hydrochloric acid (HCl) in matrix acidizing to create wormholes in carbonate formations. Previous studies demonstrated the use of ethylenediaminetetraacetic acid (EDTA), hydroxy ethylenediaminetriacetic (HEDTA), and glutamic acid-N,N-diacetic acid (GLDA) as standalone stimulation fluids to stimulate carbonate reservoirs. The main problem of using EDTA and HEDTA is their low bio-degradability. GLDA was introduced as a standalone stimulation fluid for deep carbonate reservoirs where HCl can cause corrosion and face dissolution problems. In this study, calcite cores 1.5 in. in diameter and 6 or 20 in. in length were used to determine the optimum conditions where the GLDA can break through the core and form wormholes. GLDA solutions with pH values of 1.7, 3, and 3.8 were used. The optimum conditions of injection rate and pH were determined using coreflood experiments. Damköhler number was determined using the wormhole length and diameter from the CT scan 3D and 2D images. GLDA was compared with chelates that are used in the oil industry such as EDTA and HEDTA. GLDA also was used to stimulate parallel cores with different permeability ratios (up to 6.25). GLDA was found to be very effective in creating wormholes at pH = 1.7, 3, and 3.8; at different injection rates; and at temperatures up to 300°F. Increasing the temperature increased the reaction rate and less volume of GLDA was required to break through the core and form wormholes. Unlike HCl, in GLDA there was no face dissolution or washout in the cores even at low injection rates (0.5 cm3/min). An optimum injection rate and Damköhler number were found at which the pore volume (PV) required to create wormholes was the minimum. GLDA at pH 1.7 and 3 created wormholes with a small number of PV (at 1 cm3/min, GLDA at pH 1.7 required 1.5 PV at 300°F, and at pH 3 it required 1.8 PV). Compared with acetic acid, the volume of GLDA at pH 3 required to create wormholes was less than that required with acetic acid at the same conditions. GLDA was found to be effective in stimulating parallel cores up to 6.25 permeability contrast (final permeability/initial permeability).