Experimental Investigation of Trapped Oil Mobilization with Ferrofluid

Abstract

Summary Nanoparticles have great potential to mobilize trapped oil in reservoirs because of their chemical, thermal, and interfacial properties. However, the direct application of magnetic forces on superparamagnetic nanoparticles in reservoir engineering applications has not been extensively investigated. We demonstrate the enhanced oil recovery (EOR) potential of hydrophilic superparamagnetic nanoparticles in oil production by direct observation using microfluidics. We studied the mobilization of oil blobs by a ferrofluid (a suspension of hydrophilic superparamagnetic nanoparticles in water) both in a converging/diverging micromodel channel and in a foot-long pore network micromodel, both with varying depth (so-called 2.5D micromodels). The water-based ferrofluid in all cases was the wetting fluid. Initial ferrofluid flooding experiments in single channels were performed without and then with a static magnetic field. This magnetic field caused oil droplet deformation, dynamic breakup into smaller droplets, and subsequent residual oil saturation reduction. During the flooding, after the magnetic field was applied, significant oil displacement was observed within 2 hours [6 pore volumes injected (PVI)], and 86.2% of the oil that was not mobilized without a magnetic field was mobilized within 64 hours (192 PVI). Then, in experiments in the micromodel and in a Hele-Shaw cell without flooding, we observed self-assembly of oil droplets, indicating the formation of the hydrophilic magnetic nanoparticle microstructures (chains under the magnetic field) and their interaction with the oil blobs. Further ferrofluid flooding experiments were performed in a foot-long micromodel under a rotating magnetic field. The oil saturation was reduced from 44.6 to 33.3% after 17 hours (8.5 PVI) of ferrofluid flooding after the rotating magnetic field was applied. Finally, a discussion of field application of ferrofluid flooding is presented.