Impact of Pressure-Dependent Interfacial Tension and Contact Angle on Capillary Trapping and Storage of CO2 in Saline Aquifers

Abstract

Abstract CO2 capillary trapping increases the total amount of CO2 that can be effectively immobilized in storage aquifers. This trapping, manifesting itself as accumulated CO2 columns at a continuum scale, is because of capillary threshold effects that occur below low-permeability barriers. Considering that capillary pressure is dictated by heterogeneous pore throat size, the trapped CO2 column height and associated CO2 saturation will vary spatially within a storage aquifer. This variation will be influenced by two pressure-dependent interfacial parameters: CO2-brine interfacial tension and CO2-brine-rock contact angle. Our objective is to understand how the pressure-dependence of these two parameters affects the heterogeneity of capillarity-trapped CO2 at a continuum scale. Our conceptual model is a one-dimensional two-zone system with the upper zone being a flow barrier (low permeability) and the lower zone being a flow path (high permeability). The inputs to this model include microfacies-dependent capillary pressure versus saturation curves and permeability values. The input capillary pressure curves were collected in literature that represents carbonate microfacies (dolomudstone, dolowackstone, dolopackstone, and dolograinstone) in a prevalent formation in the Permian Basin. We then employed the Leverett j-function to scale the capillary pressure curve for the two zones that are assigned with the same or different microfacies. During scaling, we considered the influence of pressure on both the interfacial tension and contact angle of CO2/brine/dolomite systems. We varied the zone permeability contrast ratio from 2 to 50. We then assumed capillary-gravity equilibriums and calculated the CO2 saturation buildup corresponding to various trapped CO2 column heights. The CO2 saturation buildup is defined as the CO2 saturation in the lower layer minus that in the upper one. We found that the saturation buildup can be doubled when varying pressure in a storage aquifer, after considering pressure-dependent interfacial tension and contact angles. Thus, assuming these two parameters to be constant across such aquifers would cause large errors in the quantification of capillary trapping of CO2. The whole study demonstrates the importance of considering pressure-dependent interfacial properties in predicting the vertical distribution of capillary-trapped CO2. It has important implications in developing a better understanding of leakage risks and consequent storage safety.