Effect of Surface Force on Nanoconfined Shale-Gas Flow in Slit Channels

Abstract

Summary A model for gas transport in nanoscale channels in shale-gas reservoirs (SGRs) is proposed using a new effective mean free path (MFP) model, which considers the effects of surface/gas interaction and the geometrical termination of a nanochannel boundary. In addition, the influences of the nanochannel dimension, formation-burial depth, surface type, and gas type on nanoconfined gas flow in slit channels are addressed. The nanoconfined gas-flow behavior is investigated for a wide range of temperature and pressure in this work because of the large prospects of shale gas in deep and ultradeep formations with pressure up to 100 MPa and temperature up to 480 K. The newly developed effective MFP model and the gas-flow-rate model are successfully validated with data from molecular dynamics (MD) simulations and experiments. Results show that the effect of surface force reduces the MFP and gas-flow capacity, which increases with a decreasing pressure, a decreasing channel size, and an increasing temperature; that the nanoconfinement effect has weaker influence on gas-transport capacity as the formation-burial depth increases and greater influence as formation pressure decreases during hydrocarbon production from SGRs; that a surface type affects the gas transport, and the gas-flow capacity in carbon (C) channels (organic channels) is stronger than that in silicon (Si) channels (inorganic channels) with the same size; and that the differences among the transport capacities of nitrogen (N2), argon (Ar), and methane (CH4) are not obvious, while the transport capacities of helium (He) are greatly lower compared with CH4 at both the SGR temperature and the laboratory temperature.