Hydrophobization of petf-surfaces for water-in-oil emulsions separations

Abstract

The technique of poly(ethylene terephthalate) track-etched membranes (PETF TMs) modification to increase of water-in-oil emulsions separations is developed. The water-in-oil emulsions separations by using PETF TMs with regular pore geometry and pore sizes 200 and 350 nm is described in the article. PETF TMs were modified with octadecyltrichlorosilane by spin-coating method to increase their hydrophobic properties. The results of changes in the pore diameters and the contact angle after PETF TMs modification are presented. The obtained samples were characterized by AFM, SEM and gas permeability test. Chloroform–water and n-hexadecane–water emulsions have been used as a test liquid for water-in-oil emulsions separations. At an operating vacuum of 700 mbar, the specific filtration performance of chloroform: water emulsions were 51.5 and 932.0 l/(m2 ⋅ h), hexadecane: water were 46.1 and 203.4 l/(m2 ⋅ h) for PETF-200 / OTS and PETF-350 / OTS, respectively. The degree of purification of emulsions by modified membranes according to the refractive index is of 100 %. Obtained membranes can be used to separate oil-water emulsions in order to prevent the corrosion of pipelines and changes of crude oil viscosity, as well as the treatment of water purification from oil industry waste.