Evaluation of influence of method for preparing on microporosity of sintered polytetrafluoroethylene-based compositions

Abstract

The aim of the work is to assess the influence of the method for preparing on the porosity of sintered polytetrafluoroethylene blanks as well as PTFE mixtures with carbon fiber and additives of powdered graphite. The article provides a comparative analysis of the method for preparing influence on the microporosity of sintered blanks made of filled and unfilled polytetrafluoroethylene. Microporosity has been determined through the comparison of the actual and theoretical (for a non-porous material) density of blanks, calculated by the methods of structural mechanics of composites. The studies made it possible to establish that the porosity of the unfilled polytetrafluoroethylene blanks pressed at a pressure of 70…80 MPa stands at 1.3 to 5.9 %. An exception was a specimen obtained by sintering in a jig, which has reached apparent density 2200 kg/m3 equal to theoretical density. It has been established, that the porosity of blanks obtained from polytetrafluoroethylene filled with shredded carbon fiber and powdered graphite stood at 0.4 to 3.9 %. An exception was a specimen with a high mass content of filler (40 %), in which the porosity was 16 %. It has been ascertained that sintering in a constrained state helps to reduce the residual microporosity for both the filled and unfilled polytetrafluoroethylene. This shows the technical efficiency of sintering in a constrained state, despite the increased labor intensity of the manufacturing process and the sophistication of technical equipment.