Direct transformation of <i>i</i>-steroid methyl ethers in 6-ketones: the use in the synthesis of brassinosteroids-Reference-Cited by-同舟云学术

Direct transformation of i-steroid methyl ethers in 6-ketones: the use in the synthesis of brassinosteroids

Published:2019-06-29 Issue:2 Volume:55 Page:175-181
ISSN:2524-2342
Container-title:Proceedings of the National Academy of Sciences of Belarus, Chemical Series
language:
Short-container-title:Vescì Akademìì navuk Belarusì. Seryâ himičnyh navuk

Author:

Gurskii A. L.¹,Zhabinskii V. N.¹,Khripach V. A.¹

Affiliation:

1. Institute of Bioorganic Chemistry of the National Academy of Sciences of Belarus

Abstract

A one-step method for the transformation of 3α,5-cyclo-6β-methyl ethers of steroids into the corresponding 3α,5-cyclo-6-ketones under the action of methyl (triﬂuoromethyl) dioxirane has been developed. The possibilities of the method have been demonstrated by preparing 3-dehydrotesterone, the biosynthetic precursor of brassinolide.

Publisher

Publishing House Belorusskaya Nauka

Subject

Inorganic Chemistry,Organic Chemistry,Chemistry (miscellaneous),Analytical Chemistry

Reference20 articles.

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