Affiliation:
1. Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Abstract
Synthesis of new asymmetric poly-π-conjugated 1-substituted derivaties of 5,5-dioxodibenzothiophene containing 1,2,3-oxadiazole fragment in the main chain of conjugation and cyclic fragments as the central chromophore are synthesized. The preparative yield of the target compounds was achieved using phosphorus (V) oxychloride as a cyclizing agent. The compounds obtained have high melting points and are blue phosphorescent luminophores.
Publisher
Publishing House Belorusskaya Nauka
Subject
Inorganic Chemistry,Organic Chemistry,Chemistry (miscellaneous),Analytical Chemistry
Reference10 articles.
1. Olkhovik V. K., Petushok V. G., Kalechits G. V. New luminescent dies from the series of 1,3,7-substituted dibenzothiophene-5,5-dions. Russian Journal of Organic Chemistry, 2011, vol. 47, no. 11, pp. 1761–1766. https://doi.org/10.1134/s1070428011110200
2. Olkhovik V. K., Vasilevskii D. A., Pap A. A., Kalechyts G. V., Matveienko Y. V., Baran A. G., Halinouski N. A., Petushok V. G. Synthesis of new polyconjugated molecules with biphenyl, dibenzothiophene, carbazole and phenanthrene units. ARKIVOC, 2008, vol. 2008, no. 9, pp. 69–93. https://doi.org/10.3998/ark.5550190.0009.908
3. Petushok V. G. Synthesis of 1-substituted 5,5’-dioxodibenzothiophene-3,7-dicarboxylic acids. Sbornik trudov molodykh uchenykh Natsional’noi akademii nauk Belarusi. T. 2 [Collection of works of young scientists of National Academy of Sciences of Belarus. Vol. 2]. Minsk, Pravo i ekonomika Publ., 2003, pp. 201–204 (in Russian).
4. Detert H., Sugiono E. Oligo(phenylenevinylene)s with increased electron affinity: 1,3,4-oxadiazoles in the main chain. Synthetic Metals, 2001, vol. 122, no. 1, pp. 19–21. https://doi.org/10.1016/S0379-6779(00)01327-8
5. Janietz, S. Anlauf S., Wedel A. New n-type rigid rod full aromatic poly(1,3,4-oxadiazole)s and their application in organic devices. Synthetic Metals, 2001, vol. 122, no. 1, pp. 11–14. https://doi.org/10.1016/S0379-6779(00)01320-5