Author:
Al-Daffay Rasha Khider Hussain,Al-Hamdani Abbas Ali Salih
Abstract
4-[(2-Amino-4-phenylazo)-methyl]-cyclo hexane carboxylic acid, a new Azo (LH2) ligand, was synthesized by reaction of the diazonium salt of trans-4-(amino-methyl) cyclo hexane carboxylic acid with 3-amino phenol. The azo ligand was characterized by micro elemental analysis (C.H.N.O.) and TGA as well as spectroscopic techniques (UV-Vis, FTIR, 1H-NMR, and LC-Mass). Atomic absorption, elemental analysis, infrared, LC-Mass, TGA, and UV-Vis spectral methods, as well as conductivity and magnetic susceptibility, were used to characterize the complexes of Ni (II), Pd (II), and Pt (IV). The following general formula has been given for the produced compounds based on the results obtained, which are as following: the Ni (II) complex has a 1:1 metal-ligand ratio, but the Pd (II) and Pt (IV) complexes have a 1:2 metal-ligand ratio.
Publisher
University of Baghdad College of Science
Subject
General Biochemistry, Genetics and Molecular Biology,General Chemistry,General Computer Science
Cited by
9 articles.
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