Chemometrics applied quantitative analysis of iron oxide mixtures by terahertz spectroscopy

Author:

Li Ying,Zhang Tian-YaoORCID,Zhang Zhao-Hui1,Yan Jian-Feng2,Zhao Xuan3,Zhao Xiao-Yan1,Li Xing-Yue,Wu Xian-Hao,Yin Lu,Yuan Yuan,Guo Jian-Mei

Affiliation:

1. Beijing Engineering Research Centre of Industrial Spectrum Imaging

2. China Ship Research and Development Academy

3. University of Science and Technology Beijing

Abstract

A quantitative analysis method for corrosion products based on terahertz spectroscopy is proposed in this paper. Mixture samples consisting of three major corrosion products (magnetite, hematite, and goethite) were prepared in 51 different concentrations. The refractive index spectra measured by terahertz time-domain spectroscopy were projected to the 2D score diagram by performing principal component analysis. The Euclidean distances between the mixtures and pure analyte on the diagram were used to build a concentration prediction model. The results indicate that the established model can precisely predict the concentration of magnetite, which is essential for a stability evaluation of the corrosion system.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Optica Publishing Group

Subject

Atomic and Molecular Physics, and Optics,Engineering (miscellaneous),Electrical and Electronic Engineering

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