Highly efficient lasing and thermal properties of Tm:Y2O3 and Tm:(Y,Sc)2O3 ceramics

Author:

Eremeev Kirill,Loiko Pavel,Maksimov Roman12,Shitov Vladislav1,Osipov Vladimir1,Vakalov Dmitry3,Lapin Viacheslav3,Camy Patrice,Chen Weidong4ORCID,Griebner Uwe4,Petrov Valentin4ORCID,Braud Alain

Affiliation:

1. Institute of Electrophysics

2. Ural Federal University named after the first President of Russia B. N. Yeltsin

3. North-Caucasus Federal University

4. Max Born Institute for Nonlinear Optics and Short Pulse Spectroscopy

Abstract

We report on thermal, spectroscopic, and laser properties of transparent 5 at.% Tm3+-doped yttria and “mixed” yttria-scandia ceramics fabricated by vacuum sintering at 1750°C using nanoparticles produced by laser ablation. The solid-solution (Tm0.05Y0.698Sc0.252)2O3 ceramic features a broadband emission extending up to 2.3 µm (gain bandwidth, 167 nm) and high thermal conductivity of 4.48 W m−1 K−1. A Tm:Y2O3 ceramic laser generated 812 mW at 2.05 µm with a slope efficiency η of 70.2%. For the Tm:(Y,Sc)2O3 ceramic, the output power was 523 mW at 2.09 µm with η = 44.7%. These results represent record-high slope efficiencies for any parent or “mixed” Tm3+-doped sesquioxide ceramics.

Funder

Agence Nationale de la Recherche

Région Normandie

Ministry of Science and Higher Education of the Russian Federation

Publisher

Optica Publishing Group

Subject

Atomic and Molecular Physics, and Optics

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