Seedless synthesis of Au nanoplates with tunable plasmonic peaks

Abstract

Au nanoplates with tunable in-plane dipolar localized surface plasmon resonance peaks in a broad range from the visible to near-infrared region were obtained in high yield using a seedless wet chemical growth method after purification. Cetyltrimethylammonium chloride was used as a surfactant, while hydrogen peroxide and sodium borohydride were used as the weak and strong reducing agents, respectively. The edge length and in-plane dipolar localized surface plasmon resonance peak of the Au nanoplates could be adjusted by varying the amounts of hydrogen peroxide and sodium borohydride. The Au nanoplates were further used as the saturable absorber to generate pulsed laser output in a passively Q-switched solid-state laser at approximately 2 µm. Our study offers a new method for obtaining Au nanoplates with tunable plasmonic peaks over a broad range.