Refractive index improvement of commercial chalcogenide glasses by external doping with Ag and Pb

Author:

Li Jialin12,Xia Kelun3,Gu Jierong3ORCID,Zheng Wenfeng12,Zhang Jingwei12,Liu Yongxing12,Yang Zhiyong4,Shen Xiang12,Liu Zijun12ORCID

Affiliation:

1. Advanced Technology Research Institute

2. Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province

3. Ningbo Institute of Oceanography

4. Hangzhou Institute of Optics and Fine Mechanics

Abstract

The refractive index of commercial chalcogenide glasses (ChGs) available in the market is generally 2.4 to 2.7, which is relatively low and has huge room for improvement. In this paper, different ratios of Ag/Pb were doped into commercial glasses by the melt-quenching method to substantially increase their refractive index. The refractive index of the commercial Ge28Sb12Se60 glass was increased from 2.6 to 3.05 by external doping with 20 atomic percentage (at%) of Ag. And the refractive index of commercially available Ge33As12Se55 glass was increased from 2.45 to 2.88 by external doping with 9 at% of Pb. These improvements effectively reduce the thickness of commercial lenses at the same radius of curvature and focal length. The physical and optical properties of commercial glasses doped with Ag/Pb in different proportions were systematically characterized.

Funder

K. C. Wong Magna Fund at Ningbo University

Analysis and Measurement Foundation of Zhejiang Province

Natural Science Foundation of Ningbo

Fundamental Research Funds for the Provincial Universities of Zhejiang

Natural Science Foundation of Zhejiang Province

Key Research and Development Program of Zhejiang Province

National Natural Science Foundation of China

Publisher

Optica Publishing Group

Subject

Electronic, Optical and Magnetic Materials

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