Manipulation of the photoluminescence of lead halide perovskite quantum dots with mechanically reconfigurable 3D photonic crystals

Abstract

Reconfigurable 3D photonic crystals (3DPCs) are promising for dynamic emission devices, owing to their unique properties. Here, we integrated the perovskite quantum dot film together with 3D reconfigurable photonic crystals (PCs) to form quantum dot/photonic crystal heterostructures and investigated their interactions at their interfaces. The photonic bandgaps of the presented 3DPCs can be dynamically tuned by heating and applying external mechanical forces, and they can be stably fixed in the intermediate states. By tuning the photonic bandgaps of the 3DPCs, a maximum photoluminescence (PL) enhancement of 11 times that of CsPb(I/Br)3 quantum dots has been achieved. It has been revealed that the combined effects of increased density of photon states and the greatly confined and enhanced electric field on the upper surface of 3DPCs contribute to the enhanced Purcell effect, which in turn leads to the enhanced photoluminescence.