Control of upconversion luminescence by tailoring energy migration in doped perovskite superlattices

Author:

Chen Wenwen1,Dong Zhengang2,Chen Haisheng1,Shen Jiaying2,Du Xiaona1,Dong Feng1,Zhou Tianhong1,Huang Wen3,Wu Zhenping2ORCID,Liu Weiwei1ORCID,Zhang Yang1

Affiliation:

1. Nankai University

2. Beijing University of Posts and Telecommunications

3. University of Electronic Science and Technology of China

Abstract

We describe an experimental investigation of photon upconversion (UC) in a series of perovskite BaTiO3/SrTiO3 superlattices doped with different lanthanide compositions. We show that UC emission can be effectively enhanced by precisely incorporating a set of lanthanide ions into separated layers rather than homogeneously distributing the dopant ions in the host lattice. The use of an inert layer in the superlattice can suppress deleterious energy cross-relaxation. Furthermore, UC emission can be rendered by controlling the energy migration mediated by the Yb-doped sublattice. These results demonstrate the opportunity to modulate energy migration and transfer processes through the rational design of superlattice structures.

Funder

National Natural Science Foundation of China

State Key Laboratory of Information Photonics and Optical Communications

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Tianjin City

Department of Science and Technology of Sichuan Province

Publisher

Optica Publishing Group

Subject

Atomic and Molecular Physics, and Optics

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