Formation, deactivation and transformation of stereospecific active sites on TiCl4/dibutylphthalate/Mg(OEt)2 catalyst induced by short time reaction with Al-alkyl cocatalyst-Reference-Cited by-同舟云学术

Formation, deactivation and transformation of stereospecific active sites on TiCl4/dibutylphthalate/Mg(OEt)2 catalyst induced by short time reaction with Al-alkyl cocatalyst

Published:2002-03 Issue:1-2 Volume:180 Page:25-34
ISSN:1381-1169
Container-title:Journal of Molecular Catalysis A: Chemical
language:en
Short-container-title:Journal of Molecular Catalysis A: Chemical

Author:

Nitta Takashi,Liu Boping,Nakatani Hisayuki,Terano Minoru

Publisher

Elsevier BV

Subject

Physical and Theoretical Chemistry,Process Chemistry and Technology,Catalysis

Reference49 articles.

1. MgCI2-Supported Ziegler-Natta Catalysts for Olefin Polymerization: Basic Structure, Mechanism, and Kinetic Behavior

2. The catalytic system Ti-complex/MgCl2

3. Investigation of a fine-grain MgCl2-supported Ziegler catalyst by stopped-flow propene polymerization: Model for the formation of active sites induced by catalyst fragmentation during polymerization

4. M. Kakugo, H. Sadatoshi, J. Sakai, in: T. Keii, K. Soga (Eds.), Catalytic Olefin Polymerization, Kodansha/Elsevier, Tokyo, 1990, p. 345.

5. Lifetime of growing polymer chain in stopped-flow propene polymerization using pre-treated Ziegler catalysts

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