Four- and five-coordinate platinum in tris[chlorotris(dimethyl sulfide)platinum(II)] pentakis(trichlorostannyl)platinate(II) from an SnCl2 insertion into a Pt

Four- and five-coordinate platinum in tris[chlorotris(dimethyl sulfide)platinum(II)] pentakis(trichlorostannyl)platinate(II) from an SnCl2 insertion into a Pt–Cl bond

Published:2004-07 Issue:1-3 Volume:697 Page:97-100
ISSN:0022-2860
Container-title:Journal of Molecular Structure
language:en
Short-container-title:Journal of Molecular Structure

Author:

Momeni Badri Z.,Amini Mostafa M.,Pape Tania,Ekkehardt Hahn F.,Ng Seik Weng

Publisher

Elsevier BV

Subject

Inorganic Chemistry,Organic Chemistry,Spectroscopy,Analytical Chemistry

Reference22 articles.

1. Transition metal-tin chemistry

2. A Study of the Mechanism of Platinum(II)/Tin(II) Dichloride Mediated Hydrogenation of Alkynes and Alkenes Employing Parahydrogen-Induced Polarization

3. Role of the trichlorostannyl ligand in homogeneous catalysis. 4. Correlations of solution structure with catalytic activity in cis-[PtCl2(L)(PR3)]/ tin chloride dihydrate (SnCl2O) and [Pt2(.mu.-Cl)2Cl2(PR3)2]/ tin dichloride dihydrate (SnCl2.2H2O)(L = PR3, CO, thioether, amine; R = aryl, alkyl). Olefin hydrogenation and hydroformylation systems

4. Role of trichlorostannyl ligand in homogeneous catalysis. 3. Solvent effects on the reactions of cis-[PtCl2(L)(PR3)] and [Pt2(.mu.-Cl)2Cl2(PR3)2] (L = CO, SMe2; R = Ph, Et) with tin dichloride dihydrate (SnCl2.2H2O)

5. Trichlorostannate complexes of platinum(II). Monitoring exchange via 2-D phosphorus-31 NMR spectroscopy

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