Synthesis and crystal and molecular structure of [(nC4H9)4N]2[MoO2(C5O5)2]; confirmation of exclusively η2-coordination by a croconate ligand
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference34 articles.
1. Coordination complexes of polyoxomolybdate anions. Characterization of a tetranuclear core from reactions in methanol: syntheses and structures of two polyoxomolybdate alcoholates, (MePPh3)2[Mo4O10(OCH3)6] and (n-Bu4N)2[Mo4O10(OCH3)2(OC6H4O)2], and their relationship to a general class of tetranuclear cluster types [Mo4Ox(OMe)2(L)y(LL)z]2-
2. Synthesis and characterization of a trinuclear polyoxomolybdate containing a reactive [MoO3] unit, [(n-C4H9)4N]2[Mo3O7(CH3C(CH2O)3)2], and its conversion to the methoxy derivative [(n-C4H9)4N][Mo3O6(OCH3)(CH3C(CH2O)3)2]
3. Synthesis and structural characterization of a binuclear oxomolybdenum(VI) tropolonate complex, (n-Bu4N)2[Mo2O6(trop)2], displaying the novel [MoO2(μ-O)2MoO2]° core
4. Polyoxomolybdate-o-benzoquinone interactions. Synthesis and structure of a diacetal derivative, [Mo4O15(OH)(C14H8)]3-, from 9,10-phenanthrenequinone carbonyl insertion. Comparison to the reaction products with tetrachloro-1,2-benzoquinone, the ligand-bridged binuclear complexes [(MoO2Cl2)2L]2-, L = (C6Cl2O4)2- and (C2O4)2-, formed via carbonyl insertion and chloride transfer
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