On the nucleophilicity of the sulphur bridges in di-μ-sulphido-tetrakis(triphenylphosphine)-diplatinum(II)
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference27 articles.
1. An example of an "inverted" tetrahedral geometry at sulfur. The synthesis and crystal and molecular structure of [HPtOs3(CO)8(.mu.4-S)(.mu.3-S)(PPh2C6H4)]2
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3. Cluster synthesis. 7. Role of bridging sulfido ligands in the synthesis of platinum osmium carbonyl cluster compounds
4. Ligand-assisted addition reactions. 1. Alkyne additions and couplings in the unsaturated cluster complexes Os4(CO)11(.mu.4-RC2CO2Me)(.mu.4-S) (R = H and CO2Me)
5. Synthesis of square-pyramidal platinum-osmium clusters by metal-metal exchange. Isolation and structural characterization of a hexanuclear intermediate
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