Inversion and proton exchange at chiral nitrogen centers of [Co(acac)2(Ph-en)]+ (acac=2,4-pentanedionate ion; Ph-en=N-phenylethylenediamine) and [Co(acac)2(Me-en)]+ Me-en=N-methylethylenediamine)-Reference-Cited by-同舟云学术

Inversion and proton exchange at chiral nitrogen centers of [Co(acac)2(Ph-en)]+ (acac=2,4-pentanedionate ion; Ph-en=N-phenylethylenediamine) and [Co(acac)2(Me-en)]+ Me-en=N-methylethylenediamine)

Published:1986-07 Issue:1 Volume:117 Page:1-4
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Kojima Masaaki,Hibino Tomomi,Ouyang Yue,Fujita Junnosuke

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference15 articles.

1. Preparation and Spectroscopic Studies of the Stereoisomers of [Co(acac)2(R1R2NCH2CH2NR3R4oro-Phenylenediamine)]+(R1–R4=H, CH3, or C6H5; acac=2,4-Pentanedionate ion) and Isomer Distribution at Equilibrium

2. Preparation and characterization of the stereoisomers of [Co(acac)2(N-phenylethylenediamine or N,N′-diphenylethylenediamine)]+ (acac = 2,4-pentanedionateIon) and isomer distribution at equilibrium

3. USE OF GLASS ELECTRODES TO MEASURE ACIDITIES IN DEUTERIUM OXIDE1,2

4. Specification of Molecular Chirality

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1. STEREOCHEMISTRY OF (R)-2-METHYLAZIRIDINE COMPLEXES OF COBALT(III) AND DIMERIZATION OF THE LIGAND;Journal of Coordination Chemistry;1997-07

2. Preparation and Characterization of [Co(tp)2(Men-en)]+(tp = Tropolonate Ion; Men-en (n= 1−4) =N-Methyl Substituted Ethylenediamine), Inversion and Deuteration at Chiral Nitrogen Centers of [Co(tp)2(Me-en or Me3-en)]+, and Crystal Structures of [Co(tp)2(N,N-Me2-en)]ClO4andΛ(R)Δ(S)-[Co(tp)2(Me-en)]ClO4;Bulletin of the Chemical Society of Japan;1992-06

3. Hydrogen isotope exchange rates for polyamines bound to inert transition-metal complexes;Coordination Chemistry Reviews;1992-05

4. Substituent Group Electronic Effects on Inversion and Proton-Exchange Rates at Chiral Nitrogen Centers for a Series of Bis(β-diketonato)(N-methylethylenediamine)cobalt(III) Complexes;Bulletin of the Chemical Society of Japan;1989-08

5. Inversion and Deuteration at the Chiral Nitrogen Centers of [Co(acac or ox)2(Me-en or Me3en)]+or−(acac=2,4-Pentanedionate Ion; ox=Oxalate Ion; Me-en=N-Methylethylenediamine, Me3en=N,N,N′-Trimethylethylenediamine);Bulletin of the Chemical Society of Japan;1989-04-15