Synthesis, structural determination and magnetic properties of three new di-μ1,3-azido copper(II) dimers derived from tridentate amines: magneto-structural correlations-Reference-Cited by-同舟云学术

Synthesis, structural determination and magnetic properties of three new di-μ1,3-azido copper(II) dimers derived from tridentate amines: magneto-structural correlations

Published:2000-02 Issue:2 Volume:298 Page:195-201
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Escuer Albert,Font-Bardı́a Mercè,Peñalba Evaristo,Solans Xavier,Vicente Ramon

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference32 articles.

1. Molecular Magnetism;Kahn,1993

2. Magnetostructural Correlations in .mu.2-1,1-N3 Bridged, Dinuclear Copper(II) Complexes. 1. Ferromagnetic and Antiferromagnetic Coupling Associated with the Azide Bridge. X-ray Crystal Structures of [Cu2(DMPTD)(.mu.2-N3)(.mu.2-Cl)Cl2].cntdot.CH3CN, [Cu2(DMPTD)(.mu.2-N3)2(N3)2], [Cu2(DIP)(.mu.2-N3)(.mu.2-Cl)Cl2].cntdot.0.5CH3OH, [Cu2(PAP46Me-H)(.mu.2-N3)(N3)2].cntdot.0.33H2O, [Cu2(PAP)(.mu.2-N3)Cl3].cntdot.CH2Cl2, [Cu2(PAP)(.mu.2-N3)(N3)(NO3)(CH3OH)](NO3).cntdot.CH3OH, [Cu2(PPD3Me)(.mu.2-N3)Cl3(H2O)1.5], and [Cu2(PPD)(.mu.2-N3)(NO3)3(H2O)1.6]

3. Strong antiferromagnetic coupling in cis-.mu.-1,3-azide-bridged copper(II) dimers: trigonal-bipyramidal vs. quadratic planar coordination with a nearly identical binucleating ligand System

4. Magneto-structural correlations in .mu.2-1,1-azide-bridged dicopper(II) complexes. 2. Dominant antiferromagnetic coupling with azide bridge angles exceeding 108.degree.. X-ray Structures of [Cu2(PAP)(.mu.2-N3)Br3].cntdot.CH2Cl2, [Cu2(PAP6Me)(.mu.2-N3)(.mu.2-Br)Br2].cntdot.1.68H2O, [Cu2(PAP6Me)(.mu.2-N3)(.mu.2-H2O)(NO3)2](NO3).cntdot.0.75CH3OH, [Cu2(PAN)(.mu.2-N3)(.mu.2-NO3)(NO3)2].cntdot.CH3OH.cntdot.CH3CN, and [Cu2(PPD35Me)(.mu.2-N3)Br3(CH3OH)]

5. Synthesis, Characterization, Spectroscopy, and Magnetism of Dinuclear Azido- and Alkoxo-Bridged Copper(II) Complexes of Bis(2-benzimidazolyl)alkanes. X-ray Structures of [Cu2(tbz)2(CH3O)2](ClO4)2(CH3OH)2, [Cu2(tbz)2(NO3)(CH3O)2](NO3)(CH3OH)2, and [Cu(tbz)(N3)2]2(CH3OH)2 (tbz = Bis(2-benzimidazolyl)propane)

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