Triple bonds between tungsten atoms with ancillary dimesitylboroalkoxide ligands. Preparations, properties and structures of W2(NMe2)4[OB(Mes)2]2 and W2(OBut)4[OB(Mes)2]2-Reference-Cited by-同舟云学术

Triple bonds between tungsten atoms with ancillary dimesitylboroalkoxide ligands. Preparations, properties and structures of W2(NMe2)4[OB(Mes)2]2 and W2(OBut)4[OB(Mes)2]2

Published:1993-11 Issue:1-2 Volume:213 Page:17-24
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Chisholm Malcolm H.,Folting Kirsten,Haubrich Scott T.,Martin James D.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference13 articles.

1. Hexakis(tert-butyldimethylsiloxy)ditungsten and its reaction with ethyne. Hydrogen atom transfer reactions involving bridging ethynyl, ethyne, vinyl and ethylidyne ligands. Crystal structures of [W2(OSiButMe2)6], [W2(OSiButMe2)6(µ-C2H2)(C5H5N)] and [W2(OSiButMe2)5(µ-CCH)]

2. Oxygen atom transfer in the reaction between hexakis(dimethyl-tert-butylsiloxy)ditungsten and nitric oxide. A remarkable difference in the reactivity of the tungsten-tungsten triple bond as a function of the attendant ligands: ButO versus ButMe2SiO

3. The preparation and characterization of M2(OEPh3)2(NMe2)4,where M = Mo and W and E = C and Si. The x-ray crystal structures of gauche-W2(OCPh3)2(NMe2)4, anti-Mo2(OCPh3)2(NMe2)4 and anti-W2(OSiPh3)2(NMe2)4

4. Synthesis and spectroscopic and structural characterization of derivatives of the quasi-alkoxide ligand [OBMes2]- (Mes = 2,4,6-Me3C6H2)

5. .pi.-Face selectivity of coordinated ketones to nucleophilic additions: the importance of aluminum-oxygen .pi.-bonding

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