Quadruply bonded complexes containing η2- or η3-tridentate phosphine ligands; syntheses, structures and 31P{1H} NMR spectra of Mo2Cl4(η3-etp)(L) and Mo2Cl4(η2-etp)2 (L = CH3OH, PMe3 and PEt3; etp = Ph2PCH2CH2P(Ph)CH2CH2PPh2)
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference17 articles.
1. Synthesis and structural characterization of Mo2Cl4(tetraphos-1)(tetraphos-1 = Ph2PCH2CH2P(Ph)CH2CH2P(Ph)CH2CH2PPh2). The first complexes of enantiomeric 1,2,5,8/1,2,6,7 type
2. Quadruply bonded dimolybdenum compounds with polydentate phosphines. 1. Mo2X4(tetraphos-1) (tetraphos-1 = Ph2PCH2CH2P(Ph)CH2CH2P(Ph)CH2CH2PPh2, X = Cl, Br), the first examples of enantiomeric 1,2,5,8/1,2,6,7 and 1,2,5,7/1,2,6,8 types
3. Quadruply bonded dimolybdenum compounds with polydentate phosphines. 2. Structural and spectroscopic properties of quadruply bonded rac-Mo2Cl4(PEt3)(.eta.3-tetraphos-2) (tetraphos-2 = tris(diphenylphosphinoethyl)phosphine)
4. Quadruply Bonded Complexes Containing Bridging Acetate and η3-Phosphine Ligands. Synthesis and Structural Characterization of Mo2(OAc)Cl3(η3-tetraphos-2) and Mo2(OAc)Cl3(η3-etp) (tetraphos-2 = P(CH2CH2PPh2)3; etp = Ph2PCH2CH2P(Ph)CH2CH2PPh2)
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