Synthesis and structures of tin(II) and lead(II) 1-aza-allyls; the [N(SiMe3)C(Ph)C(SiMe3)2]− ligand
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference41 articles.
1. Synthesis, characterisation and alkylation reactions of lanthanide β-diketiminates; crystal structures of [Nd(L–L)2Cl] and [Ce(L–L)(CHR2)2] [L–L = N(R)C(Ph)C(H)C(Ph)NR, R = SiMe3]
2. Transformation of the bis(trimethylsilyl)methyl into aza-allyl and β-diketinimato ligands; the X-ray structures of [Li{N(R)C(But)CH(R)}]2and [Zr{N(R)C(But)CHC(Ph)N(R)}Cl3](R = SiMe3)
3. Transformation of the bis(trimethylsilyl)methyl into a β-diketinimato ligand; the X-ray structure of [Li(L′L′)]2, SnCl(Me)2(L′L′) and SnCl(Me)2(LL), [L′L′= N(R)C(Ph)C(H)C(Ph)NR, LL = N(H)C(Ph)C(H)C(Ph)NH, R = SiMe3)
4. Ligand redistribution reactions as a route to cyclopentadienyl- or 1-aza-allylzirconium(IV) trichlorides and the x-ray structures of [{Cl2(μ-Cl)}2 and [2Cl2] LL′ = N(R)C(But)CHR, R=SiMe3]
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