Labilization by steric crowding. Hydrolysis and racemization kinetics of Co(tmen)33+, tmen = 2,3-diamino-2,3-dimethylbutane
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference22 articles.
1. 311. Substitution reactions in the trisethylenediaminecobalt(III) ion
2. Heterogeneous catalysis in solution. Part 16. Racemisation of (+)589-tris(ethylenediamine)cobalt(III) by a carbon black in alkaline and ethylenediamine solutions
3. The mechanism of racemization of the tris (ethylenediamine)cobalt(III) cation
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