Alkaline hydrolysis of [Co(cyclen)(O2CO)]+ and direct observation of deprotonated SN1CB intermediates
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference10 articles.
1. Kinetic study of the carbonate chelate ring opening of carbonatobisethylenediaminecobalt(III) (en)2CoCO+ in alkaline solution
2. Kinetics and mechanism of aquation and formation reactions of carbonato complexes. 14. Base-catalyzed carbonato ring opening of carbonato (.beta.,.beta.',.beta."-triaminotriethylamine) cobalt(III) perchlorate and spontaneous decarboxylation of aquobicarbonato (.beta.,B',B"-triaminotriethylamine) cobalt(III)
3. Hydrolytic reactions in carbonate systems containing tetradentate macrocyclic (N4) complexes of cobalt(III)
4. The Mechanism of the base catalysed carbonato ring opening of cis-[Co(cyclen)CO3]+
5. Kinetics and Mechanism of Ring Opening in the Hydrolysis of Cobalt(III) Carbonato Chelates
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5. Preparation, structures and reactions of isomeric [Co(cyclen)(O2C2O2)]+ and [Co(cyclen)(O2CCH2CO2)]+ complexes (cyclen = 1,4,7,10-tetraazacyclododecane) †;Journal of the Chemical Society, Dalton Transactions;2001
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